李书军个人简介

个人简介：

李书军，博士，副教授，博士生导师，河南师范大学平原学者，获河南省杰出青年科学基金、国家自然科学基金（面上、青年）等项目支持，入选河南省高校科技创新人才支持计划。主要研究方向为新型多酸材料设计合成及太阳能转化。已在Angew. Chem. Int. Ed., J. Am. Chem. Soc., Adv. Sci., 等期刊发表SCI论文60余篇，获国家授权发明专利10余项。担任《Chinese Chemical Letters》和《Polyoxometalates》期刊的青年编委，中国化学会高级会员，中国水利电力医学科学技术学会创新医药与医用材料分会理事，河南省化学会理事，河南省硼化学与先进材料重点实验室副主任。 

教育与研究经历：

2004.9—2008.7： 湖北师范大学  获理学学士学位 

2008.9—2013.7： 东北师范大学  获理学博士学位 （导师：刘术侠 教授）

2013.7— 至今： 河南师范大学化学化工学院 工作

2021.9—2022.9: Ulm University  访问学者（合作导师：Prof. Carsten Streb） 

主讲课程：

《无机化学》《无机化学实验》 

研究领域与兴趣：

多酸化学；硼化学；硼基共价有机框架

学术兼职：

Polyoxometalates 青年编委

Chinese Chemical Letters 青年编委

近年来主持的科研项目: 

1. 河南省杰出青年科学基金：多酸-有机硼酸动态框架的设计合成及光催化性能研究（252300421042,2025.1-2027.12）

2. 河南省留学人员科研择优资助 (2025) 

3. 国家自然科学基金面上项目：有机硼功能化多金属氧簇的精准合成及光催化性能研究（22171073,2022.1-2025.12）

4. 河南省高校科技创新人才支持计划：有机硼共价修饰的多酸光催化剂（23HASTIT005,2023.1-2025.12）

5. 国家自然科学基金青年项目：硼酸盐为模板的新型多金属氧酸盐的制备及光催化产氢性能（21401047, 2015.1-2017.12）

6. 中国博士后科学基金面上资助: 硼基多酸的合成及性能研究（2017M622350,2017.12-2019.3）

7. 河南省自然科学基金面上项目：有机硼酸共价功能化多酸的合成及性能研究 (202300410246, 2020.12-2021.12)

8. 河南省科技攻关项目: Ta-POMs/TiO2光解水产氢催化剂的开发和应用（182102210380,2018-2019.12）

9. 河南省教育厅科学技术研究重点项目：新型混配多酸的制备及其光催化性能研究（14A150019,2014.1-2015.12）

10. 河南师范大学博士启动金（01036500121,2014.1-2016.9）

 代表论文：

28.  Yalei Zhang, Xiaofang Su*, Tao Zheng, Waqas Ali Shah, Likai Yan* and Shujun Li,* Flexible Intervention of Polyoxometalate Support on the Electronegativity of Single Atoms to Enhance Catalytic Activity, Inorg. Chem., 2025, 64, 3824−3830. 

1.       27.  Shujun Li,* Meng-Yao Huang, Weiyi Cheng, Waqas Ali Shah, Xu-Sheng Dai, Nana Ma,* QianyiZhao* and Xuenian Chen*  An unprecedented oxalate-functionalized Ta/W polyoxometalate enabling the self-assembly of 2D composite for catalytic hydrogenation, Inorg. Chem. Front., 2024, 11, 7324. (Best Cover 2024)

2.    26.  Yupeng Zhao, Zhengfan Chen, Nana Ma, Weiyi Cheng, Dong Zhang, Kecheng Cao,Fan Feng, Dandan Gao, Rongji Liu,* Shujun Li,* and Carsten Streb,*  Atomically Engineered Defect-Rich Palladium Metallene for High-Performance Alkaline Oxygen Reduction Electrocatalysis, Adv. Sci., 2024, 2405187.

3.     25.  Jun Miao, Xiaofeng Fan, Yining Shao, Yalei Zhang, Cailing Chen, Hongrui Tian, Shujun Li*, Zhiping Zheng*, Xiaoqian Xu*, Wheel-shaped polyoxometalates as nanozymes for autophagyaugmentedand phototherapy-involved cancer nanotherapy, Journal of Pharmaceutical Analysis, 2024, 101018.

4.     24.  Waqas Ali Shah, Syed Mustansar Abbas, Muhammad Adil, Shaista Ibrahim,Qaisar Abbas Bhatti, Shujun Li,* Catalytic efficiency and kinetic analysis of manganese Polyoxometalate Heterogenized in MIL-100-Fe for selective Olefin oxidation using H₂O₂, Molecular Catalysis, 2024, 567, 114456.

 23.  Shujun Li*, Yubin Ma, Yue Zhao, Rongji Liu, Yupeng Zhao, Xusheng Dai, Nana Ma, Carsten Streb,* and Xuenian Chen*, Hydrogenation Catalysis by Hydrogen Spillover on Platinum-Functionalized Heterogeneous Boronic Acid-Polyoxometalates,  Angew. Chem. Int. Ed. 2023, e202314999.   

 (Hot Paper)  

 22.  Shujun Li*, Na Li, Gang Li, Yubin Ma, Mengyao Huang, Qingchun Xia, Qianyi Zhao*, Xuenian Chen*, Silver-modified polyniobotungstate for the visible light-induced simultaneous cleavage of C–C and C–N bonds, Polyoxometalates, 2023, 2(2): 9140024.

1.     21.  Nana Ma*, Yajing Bian, Weiyi Cheng, Yameng Li, Qingjin Wang, Shujun Li*, A theoretical exploration of the second-order NLO properties of linked sandwich double-layered metallacarboranes: charge transfer mediated by linker groups, Phys. Chem. Chem. Phys., 2023, 25, 22304.

2.     20.  Nana Ma*, Lanxin Zhou, Yameng Li, Hao Wu, Shujun Li*, Guisheng Zhang*, Theoretical Insight into the Mechanism of Cu(I)-Catalyzed [2 + 2 + 1] Cycloaddition to β‑Pyrrolinones: Azaheterocycle Formation and Assisted Dehydrogenation with Solvent MeNO₂,  J. Org. Chem., 2023, 88, 10670.

19.  YubinMa#, FanGao#, Wanru Xiao, Na Li, Shujun Li*, Bing Yu*, and Xuenian Chen*, Two transition-metal-modified Nb/W mixed-addendum polyoxometalates for visible-light-mediated aerobic benzylic C–H oxidations,  Chin. Chem. Lett., 2022, 33, 4395-4399.

18.  FanGao#, Wanru Xiao#, Shujun Li*, and Bing Yu*, Polyniobotungstate-Based Hybrid for Visible-Light-Induced Phosphorylation of N-Aryl-Tetrahydroisoquinoline, ACS Appl. Mater. Interfaces 2022, 14, 19278–19284.

4.    17. Wanru Xiao, Shujun Li,* Yue Zhao, Yubin Ma, Na Li, Jie Zhang and Xuenian Chen* Multinuclear transition metal-containing polyoxometalates constructed from Nb/W mixed-addendum precursor: synthesis, structures and catalytic performance, Dalton Trans., 2021, 50, 8690-8695.         

  ·   HOT article        ·Front cover

16.  Shujun Li*, Yue Zhao, Sebastian Knoll, Rongji Liu, Gang Li, Qingpo Peng, Pengtao Qiu, Danfeng He, Carsten Streb*, and Xuenian Chen*, High Proton-Conductivity in Covalently Linked Polyoxometalate-Organoboronic Acid-Polymers, Angew. Chem. Int. Ed. 2021, 60, 16953–16957. 

       15.  Shujun Li, Yanfang Zhou, Nana Ma, Jie Zhang, Zhiping Zheng*, Carsten Streb*, and Xuenian Chen*, Organoboron-Functionalization Enables the Hierarchical Assembly of Giant Polyoxometalate Nanocapsules, Angew. Chem. Int. Ed. 2020, 59, 8537–8540.   

   ·VIP (Very Important Paper)      · Front cover      · 被Chemistryviews做亮点介绍 

1.    14.  Shujun Li, Panpan Ji, Shangning Han,* Zhaomin Hao and Xuenian Chen*, Two polyoxoniobates-based ionic crystals as Lewis base catalysts for cyanosilylation, Inorg. Chem. Comm., 2020, 111, 107666.

13.  Shujun Li, Gang Li, Panpan Ji, Jiangwei Zhang,* Shuxia Liu, Jie Zhang and Xuenian Chen*, A Giant Mo/Ta/W Ternary Mixed-Addenda Polyoxometalate with Efficient Photocatalytic Activity for Primary Amines Coupling, ACS Appl. Mater. Interfaces, 2019, 11, 43287−43293.

12.  Shujun Li, Yue Zhao, Huihui Qi, Yanfang Zhou, Shuxia Liu, Xiaoming Ma, Jie Zhang* and Xuenian Chen*, Boronic acid derivatized lanthanide–polyoxometalates with novel B–OH–Ln and B–O–Nb bridges, Chem. Commun., 2019, 55, 2525–2528.  

1.    11.  Shujun Li, Yanfang Zhou, Qingpo Peng, Ruoya Wang, Xiaoge Feng, Shuxia Liu,* Xiaoming Ma, Nana Ma, Jie Zhang, Yi Chang, Zhiping Zheng* and Xuenian Chen*, Controllable Synthesis and Catalytic Performance of Nanocrystals of Rare-Earth-Polyoxometalates, Inorg. Chem., 2018, 57, 6624–6631.

2.    10.  Nana Ma, Changgeng Wei, Shujun Li* and Guisheng Zhang*, Theoretical insight on ethylene polymerization catalyzed by carborane-containing metal complexes: the role of carborane, Dalton Trans., 2018, 47, 14421–14425.

1.    9.  QingpoPeng, Shujun Li,*Ruoya Wang, Shuxia Liu, LinhuaXie, JianxinZhai, Jie Zhang, Qianyi Zhao and Xuenian Chen,* Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materials, Dalton Trans., 2017, 46, 4157–4160.

2.    8.  Shujun Li, Qingpo Peng, Xuenian Chen*, Ruoya Wang, Jianxin Zhai, Weihua Hu, Fengji Ma*, Jie Zhang* and Shuxia Liu, A Ta/W mixed addenda heteropolyacid with excellent acid catalytic activity and proton-conducting property, J. Solid State Chem., 2016, 243, 1–7.  

3.    7.  Fengji Ma,* Baiqing Yuan, Mengrou Li, Shujun Li,* Shuang-Shuang Zhang and Leilei Liu*, An Organic-Inorganic Hybrid Based on Keggin-Type Polyoxometalate andHypoxanthine: Synthesis, Structure, Stability, and Electrochemistry Properties, Z. Anorg. Allg. Chem., 2016, 17, 925–929.

4.     6.  Shujun Li, Fanyu Zhang, Qingpo Peng, Xuenian Chen*, Ruoya Wang, Zhifang Wang, Fengji Ma, Qianyi Zhao and Meilin Wei*, A sandwich-type POM containing mixed cations: synthesis, thermal performance and proton-conducting properties, J. Coord. Chem., 2016, 69, 425–432.

5.     5.  Shujun Li, Shuxia Liu*, Quntang, Yuhuan Gao and Xin Zhang, Borate-Mediated Self-assembly of Multinuclear Nickel(II)-containing POMs in Alkaline Buffer, Dalton Trans., 2013. 42, 13319–13322.

        4.  Shujun Li^#, Shumei Liu^# , Shuxia Liu*, Yiwei Liu, Qun Tang, Zhan Shi, Shuxin Ouyang and Jinhua Ye, {Ta₁₂}/{Ta₁₆} Clusters-Containing Polytantalotungstates with Remarkable Photocatalytic H₂ Evolution Activity, J. Am. Chem. Soc., 2012, 134, 19716−19721.  

 · 被Nature China的Research Highlights专栏亮点介绍 

1.     3.  Shujun Li, Shuxia Liu*, Nana Ma, Yongqing Qiu, Jun Miao, Congcong Li, Qun Tang and Lin Xu, Constructing nanosized polyanions with diverse structures by the self-assembly of W/Nb mixed-addendum polyoxometalate and lanthanide ion, CrystEngComm, 2012, 14, 1397–1404.   

2.     2.  Shujun Li, Shuxia Liu*, Congcong Li, Fengji Ma, Wei Zhang, Dadong Liang, Ruikang Tan, Yuanyuan Zhang and Qun Tang, Niobium-substituted arsenotungstates: controllable transformation between monomers and tetramer, Inorg Chimica Acta., 2011, 376, 296–301.

封面文章

授权专利：

1.李书军，李娜，麻娜娜，李钢，陈学年，夏庆春，一种基于银簇和Nb/W混金属多酸光催化剂及其制备方法和应用，专利号ZL 2022 1 0972432.3

2.李书军，李钢，麻娜娜，陈学年，张絜，Ta/W/Mo三元混配型多金属氧酸盐及其在光催化伯胺偶联反应中的应用，专利号201911012604.7

3.李书军，周艳芳，赵月，李钢，陈学年，一种具有可见光催化活性的Ta/W混配型多酸有机-无机杂化物及其制备方法，专利号2018106373243.4

4.李书军，周艳芳，陈学年，赵月，李钢，一种混配型杂多酸有机-无机化合物，制备方法及其在可见光催化降解染料废水中的应用，专利号201810980354.5

5.李书军，王若雅，彭青坡，翟建新，陈学年，一类钽基稀土多酸及其纳米晶的制备方法，专利号201710766224.7

6.李书军，汲盼盼，王若雅，翟建新，陈学年，一种杂多铜铌酸盐及其制备方法和在光催化降解染料废水中的应用，专利号201610937368.X

7.李书军，彭青坡，陈学年，翟建新，张絜，Ta/W混配型杂多酸，制备方法及其在酸催化和质子导电中的应用，专利号201610808988.3

8.李书军，彭青坡，陈学年，王若雅，张絜，一类B/POMs/TiO₂三元复合光催化材料及其制备方法，专利号201510453806.0

获奖情况：

2022年，河南省优秀科技论文一等奖

2021年，河南省自然科学优秀论文二等奖

2021年，河南师范大学国家级项目2021年度先进个人

2017年，指导本科生获第十三届“挑战杯”河南省大学生课外学术科技作品竞赛二等奖

2017年，在指导研究生开展科研创新工作中，被评为河南师范大学“优秀指导教师”

2017年，指导研究生获得2017年“挑战杯”河南师范大学大学生课外学术科技作品竞赛三等奖

2016年，河南师范大学文明教师

2012年，博士生国家奖学金

2012年，吉林省科学技术一等奖