个人简介:
李志勇,河南师范大学平原学者,博士生导师。主要从事离子液体与低碳能源相关研究,任中国化工学会化工大数据与智能设计专业委员会委员,中国化学会化学热力学与热分析专业委员会第一届青年委员会副主任,入选河南省高层次人才(C类),河南省高校科技创新人才支持计划,河南省高校青年骨干教师培养计划,河南省教育厅学术技术带头人,被聘为Green Energy Environ. 和盐湖研究两个期刊的青年编委。先后在Angew. Chem., Green Chem., TRAC Trends Anal. Chem., Phys. Chem. Chem. Phys.等国际重要期刊发表SCI论文100余篇,论文被SCI他引4000余次,获河南省自然科学奖一等奖1项,入选全球前2%顶尖科学家榜单(World’s Top 2% Scientists 2022, 2023,斯坦福大学)。
E-mail:lizhiyong03@126.com; yli@htu.edu.cn
ORCiD:0000-0002-1865-864X Scopus Author ID: 57022563800
欢迎有志从事离子液体、绿色化学、低碳能源等领域研究的同学加盟!长期招聘博士后加盟合作。
教育经历:
2003.09-2007.06 河南师范大学化学与环境科学学院 化学 理学学士
2007.09-2010.06 河南师范大学化学与环境科学学院 物理化学 理学硕士
2013.09-2019.06 河南师范大学化学化工学院 物理化学 理学博士
工作经历:
2010.07 至今 河南师范大学化学化工学院讲师、副教授
2019.10 遴选为硕士生导师
2022.12 遴选为博士生导师
主讲课程:
《物理化学》、《物理化学实验》、《化学信息学》、《现代化学进展》、《科技文献检索与论文写作》
研究领域与兴趣:
1.功能化离子液体,重点关注生物相容性离子液体、光响应离子液体等领域
2.刺激响应乳液,包括乳状液、微乳液、Pickering乳液
3.气体捕集与分离,面向碳中和,开展二氧化碳、氨气等气体捕集与分离
近年来主持的主要科研项目:
1.国家自然科学基金:紫外/可见光对离子液体乳状液结构和相行为的调控,项目编号:21803017, 2019.1-2021.12, 26万元
2.国家自然科学基金:螺吡喃型离子液体微乳液的结构和相行为的可逆光调控,项目编号:22273016, 2023.1-2026.12, 54万元
3.河南省高校科技创新团队:基于离子液体的绿色分离,项目编号:25IRTSTHN002,2025.1-2027.12, 50万元
4.河南省高校科技创新人才,光响应离子液体双水相,项目编号:21HASTIT003, 2021.1-2023.12, 30万元
代表性论文:
35. Shuaiqi Gao, Yingying Yang, Liyong Zhai, Yang Zhao,* Zhiyong Li, * Huiyong Wang, Jianji Wang*, Alkoxy-functionalized covalent organic Framework membranes for efficient molecular sieving with high water permeance, Sep. Purif. Technol., 2025, 356, 129903.
34. Zhiyong Li, Zhenzhen Wang, Doudou Cao, Yunlei Shi, Yuling Zhao, Huiyong Wang,* Jianji Wang*,Designing bimetallic ionic liquid hybridized molecular sieve adsorbents for efficient ammonia adsorption at high temperature and low content, Sep. Purif. Technol., 2025, 354, 128861.
33. Ruipeng Li, Jingnuo Shi, Xing Zhou, Zhiyong Li*, Yanfei Zhao, Zhimin Liu, and Jianji Wang*, Green Synthesis of Nitriles from Biomass-Derived Aldehydes by Evoking Intrinsic Cooperative Effects of Ionic Liquids, ACS Sustain. Chem. Eng., 2024, 12, 11338–11346.
32. Panpan Zhou, Zhiyong Li*, Zhenzhen Wang, Huiyong Wang, Yang Zhao, Jianji Wang*, Sunlight assisted highly efficient desorption of ammonia by redox graphene hybrid metal–organic framework photothermal conversion adsorbents, Sep. Purif. Technol., 2024, 336, 126348
31. Xiaoyan Pei, Wangyue Song, Yang Zhao and Zhiyong Li*, CO2-switchable amidine-modified ZIF-90- stabilized Pickering emulsions for controllable Knoevenagel condensation reactions, Mol. Syst. Des. Eng., 2024, 9, 278-285.
30. Xiaoyan Pei*, Wangyue Song, Yunlei Shi, Yang Zhao, Zhiyong Li*, CO2-triggered (3-aminopropyl)triethoxysilane-functionalized M-MOF-74 stabilized Pickering emulsions, J. Mol. Liq., 2024, 405, 125022.
29. Liufang Zhao, Xiaoqing Yuan, Huiyong Wang, Yuanchao Pei, Yunlei Shi, Yuling Zhao, Yang Zhao*, Zhiyong Li*, Light-switchable emulsions: From reversible emulsificationdemulsification to controllable microreactors, J. Mol. Liq., 2023, 372, 121166.
28. Xiaoyan Pei*, Wangyue Song, Yunlei Shi, Chao Xu, Zhe Wang, Xiantao Ma, Dong-Li Xu, and Zhiyong Li*, CO2-Switchable Emulsification and Demulsification of Pickering Emulsion Stabilized by Zirconium-Based Metal–Organic Frameworks, ACS Sustain. Chem. Eng., 2023 11, 796-803.
27. Zhiyong Li, Kairui Shi, Liyong Zhai, Zhenzhen Wang, Huiyong Wang, Yang Zhao*, Jianji Wang*, Constructing multiple sites of metal-organic frameworks for efficient adsorption and selective separation of CO2, Sep. Purif. Technol., 2023, 307, 122725.
26. Yilong Li, Zhiyong Li*, Ruipeng Li, Huiyong Wang, Yang Zhao, Yuanchao Pei, Jianji Wang*, Highly efficient triiodide ion adsorption from water by ionic liquid hybrid metal–organic frameworks, J. Mol. Liq., 2023, 370, 121009.
25. Zhiyong Li, Yu Chen, Zhenzhen Wang, Yang Zhao, Qingchun Xia, Jikuan Qiu, Huiyong Wang*, Jianji Wang*, Ionic liquid hybrid metal–organic frameworks for efficient adsorption and selective separation of ammonia at high temperature, Chem. Eng. J., 2023, 464, 142728.
24. Chaojie Pang, Jiage Liu, Rui Peng, Yingying Guo, Zhiyong Li*, Huiyong Wang*, Liquid-phase exfoliation of titanium disulfide nanosheets in aqueous ionic liquid solutions for highly efficient CO2 electroreduction, J. Mol. Liq., 2023, 381, 121814.
23. Xiaoyan Pei*, Wangyue Song, Dong-Li Xu, Qiuju Zhou, Yang Zhao, and Zhiyong Li*, CO2-induced phase transfer of amino-modified ZIF-90 between immiscible liquid phases for recyclable efficient synergistic catalysis, ACS Appl. Nano Mater., 2023, 6, 13, 11291-11298.
22. Ruipeng Li, Xing Zhou, Zhiyong Li*, Yuepeng Wang, Yanfei Zhao, Zhimin Liu*, Changling Yan, Cailing Wu, Yang Zhao, and Jianji Wang*, Intramolecular dehydration of cyclic alcohols to cyclic alkenes via cation- and anion-confined catalysis over ionic liquids, ACS Sustain. Chem. Eng., 2023, 11, 29, 10659-10666.
21. Xiaoyan Pei*, Wangyue Song, Zongwen Zhang, Yang Zhao, and Zhiyong Li*, CO2-Responsive CuI-Ionic Liquid/Zeolitic Imidazolate Frameworks Stabilized Pickering Emulsions for Azide–Alkyne Click Reaction, ACS Appl. Nano Mater., 2023, 6(21), 19972-19980.
20. Xiaoyan Pei, Zhiyong Li*, Huiyong Wang, Qiuju Zhou, Zuodong Liu, and Jianji Wang* CO2-Switchable Phase Separation of Nonaqueous Surfactant-Free Ionic Liquid-Based Microemulsions, ACS Sus. Chem. Eng., 2022, 10, 1777-1785.
19. Zhenzhen Wang, Zhiyong Li*, Huiyong Wang, Yang Zhao, Qingchun Xia, Jikuan Qiu, and Jianji Wang*, Regulating the Pore Microenvironment of Microporous Metal–Organic Frameworks for Efficient Adsorption of Low-Concentration Ammonia, ACS Sus. Chem. Eng., 2022, 10(33), 10945-10954. (most popular article)
18. Xiaoyan Pei*, Chunyu Tian, Yanning Wang, Zhenzhen Li, Zhiyan Xiong, Huiyong Wang, Xiantao Ma, Xinhua Cao and Zhiyong Li*, CO2-Driven reversible transfer of amine-functionalized ZIF-90 between organic and aqueous phases, Chem. Commun., 2022, 58, 10372-10375.
17. Zhenzhen Wang, Zhiyong Li*, Xia-Guang Zhang, Qingchun Xia, Huiyong Wang, Chenlu Wang, Yanlei Wang, Hongyan He, Yang Zhao, and Jianji Wang* Tailoring Multiple Sites of Metal–Organic Frameworks for Highly Efficient and Reversible Ammonia Adsorption, ACS Appl. Mater. Interfaces, 2021, 13, 56025-56034.
16. Xiaoyan Pei*, Jiang Liu, Weihao Rao, Xiantao Ma, and Zhiyong Li*, CO2-Switchable Reversible Phase Transfer of Carbon Dots, Ind. Eng. Chem. Res., 2021, 60(25), 9296-9303.
15. Doudou Cao, Zhiyong Li*, Zhenzhen Wang, Huiyong Wang, Shuaiqi Gao, Yu Wang, Yunlei Shi, Jikuan Qiu, Yang Zhao, Jianji Wang,* Highly Dispersed Ionic Liquids in Mesoporous Molecular Sieves Enable a Record NH3 Absorption, ACS Sus. Chem. Eng., 2021, 9, 16363-16372.
14. Zhiyong Li, Yunlei Shi, Anlian Zhu, Yuling Zhao, Huiyong Wang, Bernard P. Binks* and Jianji Wang*, Light-responsive, reversible emulsification and demulsification of oil-in-water Pickering emulsions for catalysis. Angew. Chem. Int. Ed., 2021, 60, 3928-3933.
13. Huiyong Wang, Jingjing Cui, Yuling Zhao, Zhiyong Li*, Jianji Wang*, Highly efficient separation of 5-hydroxymethylfurfural from imidazolium-based ionic liquids, Green Chem., 2021, 23, 405-411.
12. Zhiyong Li, Anqi Li, Yifan Zhou, Lujun Zhang, Yang Zhao,* Xiaopeng Xuan,* From hydrophobity to hydrophilicity: Design, synthesis, structural transformation and distinguishment of highly symmetric 1,3-bis(carboxymethyl)imidazolium bis(trifluoromethyl)sulfonyl)amide ionic liquids, J. Mol. Struc., 2021, 1231, 129688.
11. Zhiyong Li, Ying Feng, Xiaomin Liu, Huiyong Wang,* Yuanchao Pei, H. Q. Nimal Gunaratne and Jianji Wang*, Light-triggered switchable ionic liquid aqueous two-phase systems, ACS Sus. Chem. Eng., 2020, 8, 15327-15335.
10. Zhiyong Li, Ruipeng Li, Xiaoqing Yuan, Yuanchao Pei, Yuling Zhao, Huiyong Wang, Jianji Wang*, Anionic structural effect in liquid-liquid separation of phenol from model oil by choline carboxylate ionic liquids. Green Energy Environ., 2019, 4, 131-138.
9. Zhiyong Li, Ying Feng, Xiaoqing Yuan, Huiyong Wang, Yuling Zhao, Jianji Wang*, Photo-triggered reversible phase transfer of azobenzene-based ionic liquid surfactants between oil and water. Int. J. Mol. Sci., 2019, 20, 1685.
8. Xiaoqing Yuan, Zhiyong Li*,Ying Feng, Yuanchao Pei, Huiyong Wang, Diandian, Liu, Dayu Wang, Jianji Wang*. Phase behavior and microstructure of azobenzene ionic liquids based photo-responsive microemulsions. J. Mol. Liq., 2019, 227, 805-811.
7. Zhiyong Li, Ying Feng, Xiaoqing Yuan, Yuling Zhao, Jianji Wang*, Structure and performance modulation of photo-responsive ionic liquids. Prog. Chem.(化学进展), 2019, 31, 1550-1559.
6. Zhiyong Li, Xiaoqing Yuan, Ying Feng, Yongkui Chen, Yuling Zhao, Huiyong Wang, Qingli Xu, Jianji Wang*, A reversible conductivity modulation of azobenzene-based ionic liquids in aqueous solutions by UV/Vis light, Phys. Chem. Chem. Phys., 2018, 20, 12808-12816.
5. Zhiyong Li, Huiyong Wang, Mengen Chu, Pengxin Guan, Yang Zhao, Yuling Zhao, Jianji Wang*, Photo-isomerization and light-modulated aggregation behavior of azobenzene-based ionic liquids in aqueous solutions, RSC Adv., 2017, 7, 44688-44695.
4. Zhiyong Li, Yuanchao Pei, Huiyong Wang, Yuling Zhao, Jianji Wang*, Progress in environmentally friendly ionic liquids aqueous two-phase systems. Chin. Sci. Bull.(科学通报), 2015, 60: 1-9
3. Zhiyong Li, Xinxin Liu, Yuanchao Pei, Jianji Wang*, Mingyuan He. Design of environmentally friendly ionic liquids aqueous two-phase systems for the efficient and high activity extraction of proteins. Green Chem., 2012, 14, 2941-2950.
2. Zhiyong Li, Yuanchao Pei, Huiyong Wang, Jing Fan, Jianji Wang*.Ionic liquids based aqueous two-phase systems and their applications in green separation process. TRAC Trends Anal. Chem., 2010, 29, 1336-1346.
1. Zhiyong Li, Yuanchao Pei, Li Liu, Jianji Wang*. (Liquid+liquid) equilibria for (acetate-based ionic liquids + inorganic salts) aqueous two-phase systems. J. Chem. Thermodyn., 2010, 42, 932-937.
获得荣誉与奖励:
1. 《离子液体双水相对某些生物分子的萃取分离性能研究》河南省优秀硕士学位论文,2010年
2. 《Ionic liquids based aqueous two-phase systems and their applications in green separation process》河南省首届自然科学优秀学术论文一等奖,2011年
3. 《(Liquid+liquid) equilibria for (acetate-based ionic liquids + inorganic salts) aqueous two-phase systems》河南省首届自然科学优秀学术论文二等奖,2011年
4.离子液体与绿色过程青年新秀,中国化工学会离子液体专业委员会,2017年
5.离子液体的介观结构、性行为及性能调控,河南省教育厅科技成果一等奖,2021年,第三完成人
6.离子液体的介观结构、性行为及性能调控,河南省自然科学奖一等奖,2021年,第三完成人
7. ISPT 2024 青年科学家奖,2024年