教师简介

姓名:曹治国

职务:院长

职称:教授

电子邮箱:wq11ab@163.com


个人简历

曹治国,博士,教授,博士生导师。主要从事新污染物环境和健康风险相关研究。先后主持国家自然科学基金青年科学基金项目(B类)[原优秀青年科学基金项目]、面上项目、青年基金项目,河南省杰出青年科学基金、中国博士后科学基金特别资助项目等国家和省部级项目10余项。荣获国家优青、欧盟玛丽居里学者、中国环境科学学会“最美科技工作者”、新乡市最美科技工作者、中原青年拔尖人才、河南省优秀青年科技专家、河南省青年科技奖、河南省高校科技创新人才、河南省教育厅学术技术带头人等荣誉和奖励。近年来,在国内外期刊发表论文160余篇,累计被引用5400余次,其中以第一/通讯作者发表SCI论文50余篇,h-index37。担任河南省环境科学学会副理事长,河南省化学会常务理事,中国环境科学学会新污染物治理专委会常务委员,中国环境科学学会POPs专委会委员,Global Environmental Science等多个刊物的副主编、编委。


教育/工作经历

工作经历:

2023.04–至今,河南师范大学,环境学院,教授

2018.04 2023.03,河南师范大学,环境学院,副教授

2014.07–2018.03,河南师范大学,环境学院,讲师

2013.05–2013.06,比利时安特卫普大学,合作研究(合作人为著名环境化学家Adrian Covaci教授)

2011.11–2011.12,联合国环境规划署,合作研究(合作人为著名环境化学家Heidelore Fiedler教授)

教育经历:

2010.09–2014.06,清华大学,博士,导师: 余刚 教授

2007.09–2010.06,北京师范大学,硕士,导师: 刘静玲 教授

2003.09–2007.06,武汉理工大学,学士,导师: 刁红丽 教授


研究领域

环境地球化学

新污染物环境和健康风险评估

新型持久性有机污染物暴露干预和风险削减措施制定


主要学术及社会兼职

担任河南省环境科学学会副理事长,河南省化学会常务理事,中国环境科学学会新污染物治理专委会常务委员,中国环境科学学会POPs专委会委员等。担任Global Environmental Science等多个刊物的副主编、编委。Environmental Health Perspectives, Environment International, Journal of Hazardous Materials, Environmental Pollution等多个国内外期刊的审稿人。


科研项目情况

主持项目:

[1] 曹治国. 室内污染物环境暴露学(42122057, 2022.1-2024.12). 国家自然科学基金优秀青年科学基金.

[2] 曹治国. 中原城市群高风险新污染物的甄别及风险评估(252300421080, 2025.01-2027.12), 河南省杰出青年科学基金.

[3] 曹治国, 余浩, 蔡稳稳, 赵磊成. 典型环境来源有机磷酸酯的透皮规律、生物有效性及基于角质层的皮肤暴露风险研究(42477473, 2025.01-2028.12). 国家自然科学基金面上项目.

[4] 曹治国, 闫广轩, 余浩, 贾晨辉, 李静华, 程轲, 刘桓嘉, 杜俊平, 贾志鹏, 李振华. 河师大国控站PM10污染成因与精准防控(2022年度), 新乡市重大科技专项.

[5] 曹治国. 基于多介质同步观测的阻燃剂人体暴露路径、模式及季节性规律研究. (ZYYCYU202012168, 2021.01-2023.12). “中原英才计划”-中原青年拔尖人才.

[6] 曹治国. 891689—FluoroCosm (224934 EUR, 2020.9-2022.8). 欧盟研究委员会.

[7] 曹治国, 彭建彪, 闫广轩, 沈墨海. -霾对典型人群阻燃剂真皮暴露的影响规律、作用机制和干预措施研究(41977308, 2020.1-2023.12). 国家自然科学基金面上项目.

[8] 曹治国. 霾污染对阻燃剂人体真皮暴露模式及健康风险的影响(20HASTIT011, 2020.1-2021.12). 河南省教育厅高校科技创新人才支持计划.

[9] 曹治国. 灰霾强度对室内空气中新型阻燃剂赋存分配及人体暴露模式的影响(21607038, 2017.01-2019.12). 国家自然科学基金青年基金项目.

[10] 曹治国. 不同霾污染强度下儿童对溴、磷代阻燃剂的环境暴露模式(2016T90668, 2016.6-2018.6). 国家博士后基金特别资助项目.



代表性论文

[1] Du F, Hou M, Lu S, Ding X, Zhang L, Du Y, An Z, Cai W, Zhao L, Wu W*, Cao Z*. Toxicity enhancement of microplastics released from food containers through thermal aging: Absorbing more serum proteins thus activating the innate immune response via actin polymerization [J]. Environment International, 2025, 197: 109358.

[2] Hu P.#, Zhong S.#, Guo J., Wang M., Shi S., Liu D., Yu H., Zhu F., Li Y., Cao Z.*. Global human exposure of atmospheric polybrominated diphenyl ethers: Variation patterns of exposure pathways and phase contributions [J]. Environment International, 2025, 195: 109248.

[3] Zhang S.#, Hu P.#, Xu X., Guo J., Wang Y., Huang Y., Yu H., Hou G., Liu D., Zhao Y., Cao Z.*. Mechanisms of haze influencing phase distribution and human exposure to airborne flame retardants with different uses: Emission, partition, and dry deposition [J]. Journal of Hazardous Materials, 2025, 489: 137491.

[4] Lu P., He R., Wu Y., Wu B., Li H., He C., Lin M., Wang M., Cai W., Shen X., Li G., Cao Z.*, An T.*. Urinary metabolic alterations associated with occupational exposure to metals and polycyclic aromatic hydrocarbons based on non-target metabolomics [J]. Journal of Hazardous Materials, 2025, 487: 137158.

[5] Zhu C.#, Cao Z.#, Hu B., Li Z., Huang S., Han X., Luo X., Yuan H., Li L.*. Human bare and clothing-covered skin exposure to chlorinated paraffins for the general populations: Exposure pattern differential and significance of indirect dermal exposure via clothing-to-skin transport [J]. Environment International, 2024, 192: 109068.

[6] Liu M.*, Wang B., Yi S., Dou X., Zhang Y., Yu H., Zhang X., Dong S., Feng J.*, Cao Z.*, Zhu L. Novel insights into the mechanisms of bioaccumulation and tissue-specific distribution of hexafluoropropylene oxide homologues, novel PFOA alternatives, in zebrafish (Danio rerio) [J]. Environment International, 2024, 192: 175492.

[7] Hou G., Wang Q., Li N., Zhao Y., Wang Z., Shi S., Liu D., Zhang Y., Hu P., Zhao L.*,Cao Z.*. Face mask as an indicator and shield of human exposure to traditional and novel organophosphate esters [J]. Environment International, 2024, 183: 108389.

[8] Wang Z., Geng S., Zhang J., Yang H., Shi S., Zhao L., Luo X.*, Cao Z.*. Methods for the characterisation of dermal uptake: Progress and perspectives for organophosphate esters [J]. Environment International, 2024, 183: 108400.

[9] Cao Y.#, Cao Z.#, Wang P., Zhao L., Zhang S., Shi Y., Liu L., Zhu H., Wang L., Cheng Z.*, Sun H. Source and bioavailability of quaternary ammonium compounds (QACs) in dust: Implications for Nationwide Exposure in China [J]. Journal of Hazardous Materials, 2024, 480: 136268.

[10] Wang M., Wang Y., Lv Y., Tang J., Wei P., Lu P., Zhao L., Li G., Cao Z.*, An T.*. Quantitative characterization of resident' exposure to typical semi-volatile organic compounds (SVOCs) around a non-ferrous metal smelting plant [J]. Journal of Hazardous Materials, 2024, 465: 133353.

[11] Wang X.*, Luo X., Li R., Chang Y., Peng J., Wang W., Liu H., Yan G., Wei P., Cao Z.*. Boosting peroxymonosulfate activation over partial Zn-substituted Co3O4 for florfenicol degradation: Insights into catalytic performance, degradation mechanism and routes [J]. Chemical Engineering Journal, 2024, 491: 152197.

[12] Wang X.*, Li R., Luo X., Mu J., Peng J., Yan G., Wei P., Tian Z., Huang Z., Cao Z.*. Enhanced CO oxidation performance over hierarchical flower-like Co3O4 based nanosheets via optimizing oxygen activation and CO chemisorption [J]. Journal of Colloid and Interface Science, 2024, 654(part A): 454-465.

[13] Sun M., Wang Z., Cao Z.*, Dong Z.*. Infants exposure to chemicals in diapers: A review and perspective [J]. Science of The Total Environment, 2024, 953: 176072.

[14] Yu H.*, Li M., Zheng X., Zhu M., Zheng Z., Xie T., Yan G., Hu P., Cao Z.*, Feng J., Sun J. Potential source and health risks of black carbon based on MERRA-2 reanalysis data in a typical industrial city of North China Plain [J]. Journal of Environmental Management, 2024, 354: 120367.

[15] Shi S., Feng Q., Zhang J., Wang X., Zhao L., Fan Y., Hu P., Wei P., Bu Q., Cao Z.*. Global patterns of human exposure to flame retardants indoors [J]. Science of The Total Environment, 2024, 912: 169393.

[16] Zhao Y., Fan Y., Li J., Liu Y., Lv Y., Zhao L., Hou G., An Z., Cai W., Li X., Wu W.*, Cao Z.*. Assessment of Human Exposure to Traditional and Novel Organophosphate Esters via Multiple Personal Matrices [J]. Environmental Science & Technology, 2023, 58(7): 3332-3341.

[17] Peng J.*, Chang Y., Xu L., Zhang Y., Wang T., Wang X., Liu H., Yan G., Gao S., Liu D., Cao Z.*. Insights into the enhanced removal of sulfamethoxazole via peroxymonosulfate activation catalyzed by bimetallic (Co/Cu) doped graphitic carbon nitride: Reaction kinetics, mechanisms, and pathways [J]. Chemical Engineering Journal, 2023, 476: 146692.

[18] Zhang Y., Wu M., Xu M., Hu P., Xu X., Liu X., Cai W., Xia J., Wu D., Xu X., Yu G.*, Cao Z.*. Distribution of flame retardants among indoor dust, airborne particles and vapour phase from Beijing: spatial-temporal variation and human exposure characteristics. Environment International, 2022, 170: 107557.

[19] Peng J.*, Wang Z., Wang S., Liu J., Zhang Y., Wang B., Gong Z., Wang M., Dong H., Shi J., Liu H., Yan G., Liu G., Gao S., Cao Z.*. Enhanced removal of methylparaben mediated by cobalt/carbon nanotubes (Co/CNTs) activated peroxymonosulfate in chloride-containing water: Reaction kinetics, mechanisms and pathways [J]. Chemical Engineering Journal, 2021, 409: 128176.

[20] Fan Y., Chen Q., Wang Z., Zhang X., Zhao J., Huang X., Wei P., Hu P., Cao Z.*. Identifying dermal exposure as the dominant pathway of children's exposure to flame retardants in kindergartens [J]. Science of the Total Environment, 2021, 808: 152004.

[21] Cao Z.*, Wu X., Wang T., Zhao Y., Zhao Y., Wang D., Chang Y., Wei Y., Yan G., Fan Y., Yue C., Duan J., Xi B.*. Characteristics of airborne particles retained on conifer needles across China in winter and preliminary evaluation of the capacity of trees in haze mitigation [J]. Science of the Total Environment, 2021, 806(Part 2): 150704.

[22] Shen M., Ren M., Wang Y., Shen F., Du R., Quan L., Wei Y., Zhang T.*, Li J., Yan G., Peng J., Cao Z.*. Identifying dust as the dominant source of exposure to heavy metals for residents around battery factories in the Battery Industrial Capital of China [J]. Science of the Total Environment, 2021, 765: 144375.

[23] Yue C., Cui K., Duan J., Wu X., Yan P., Rodriguez C., Fu H., Deng T., Zhang S., Liu J., Guo Z., Xi B.*, Cao Z.*. The retention characteristics for water-soluble and water-insoluble particulate matter of five tree species along an air pollution gradient in Beijing, China [J]. Science of the Total Environment, 2021, 767: 145497.

[24] Cao Z., Wang M., Shi S., Zhao Y., Chen X., Li C., Li Y., Wang H., Bao L., Cui X.*. Size-distribution-based assessment of human inhalation and dermal exposure to airborne parent, oxygenated and chlorinated PAHs during a regional heavy haze episode [J]. Environmental Pollution, 2020, 263(Pt A): 114661.

[25] Cao Z.*, Zhao L., Zhang Y., Ren M., Zhang Y., Liu X., Jie J., Wang Z., Li C., Shen M., Bu Q.*. Influence of Air Pollution on Inhalation and Dermal Exposure of Human to Organophosphate Flame Retardants: A Case Study During a Prolonged Haze Episode. Environmental Science & Technology, 2019, 53(7): 3880-3887.

[26] Cao Z.*, Chen Q., Zhu C., Chen X., Wang N., Zou W., Zhang X., Zhu G., Li J., Mai B., Luo X.*. Halogenated Organic Pollutant Residuals in Human Bared and Clothing-Covered Skin Areas: Source Differentiation and Comprehensive Health Risk Assessment. Environmental Science & Technology, 2019, 53(24): 14700-14708.

[27] Cao Z.*, Wang M., Chen Q., Zhu C., Jie J., Li X., Dong X., Miao Z., Shen M., Bu Q.*. Spatial, seasonal and particle size dependent variations of PAH contamination in indoor dust and the corresponding human health risk [J]. Science of the Total Environment, 2019, 653: 423-430.

[28] Cao Z.*, Chen Q., Ren M., Zhang L., Shen F., Wang X., Shi S., Zhao Y., Yan G., Peng J. Higher health risk resulted from dermal exposure to PCBs than HFRs and the influence of haze [J]. Science of the Total Environment, 2019, 689: 223-231.

[29] Cao Z.*, Chen Q., Li X., Zhang Y., Ren M., Sun L., Wang M., Liu X.*, Yu G.*. The non-negligible environmental risk of recycling halogenated flame retardants associated with plastic regeneration in China [J]. Science of the Total Environment, 2019, 646: 1090-1096.

[30] Cao Z., Zhao L., Meng X., Liu X., Wu P., Fan X., Wang S., Jie J., Miao Z., Xu X., Shen M.*, Bu Q.*. Amplification effect of haze on human exposure to halogenated flame retardants in atmospheric particulate matter and the corresponding mechanism [J]. Journal of Hazardous Materials, 2018, 359: 491-499.

[31] Cao Z., Wang M., Chen Q., Zhang Y., Dong W., Yang T., Yan G., Zhang X., Pi Y., Xi B.*, Bu Q.*. Preliminary assessment on exposure of four typical populations to potentially toxic metals by means of skin wipes under the influence of haze pollution [J]. Science of the Total Environment, 2018, 613-614: 886-893.



 授权发明专利

[1] 曹治国,王萌萌,全丽俊,赵友华,施世宇,王丹阳,常宇,王嫣格,黄新雨,杜若锦. 基于胶带法研究人体附着物形态分布和载荷的方法及装置,授权发明专利,专利授权号:ZL 201910713521.4,授权公告日:2024.11.29.

[2] 曹治国,张亚洁,孟雪洁,赵磊成,张敏,王书亭,王萌萌,陈巧莹,张鑫,沈墨海,张亚彩. 一种可以用于采集空气中颗粒物的口罩,授权发明专利,专利授权号:ZL 201810428673.5,授权公告日:2024.01.30.

[3] 曹治国,赵磊成,张亚洁,张亚彩,李逍逍,任美慧,苗正,王萌萌,陈巧莹,沈墨海. 一种用于手掌灰尘样品采集以用于真皮暴露评估的手套,授权发明专利,专利授权号:ZL 201810857539.7,授权公告日:2023.07.25.

[4] 曹治国,陈巧莹,任美慧,王丹阳,赵友华,陈茜,王能,施世宇,王嫣格,王萌萌,吴欣源,许骁鹏. 一种基于擦拭取样评估人体FRs真皮暴露量的模型,授权发明专利,专利授权号:ZL 201910726860.6,授权公告日:2023.03.31.

[5] 曹治国,王萌萌,苗正,董夏妍,节建业,王志宇,沈方方,张玲,李逍逍,李常贺. 通过标准曲线评估附着在人体手部灰尘质量的方法,授权发明专利,专利授权号:ZL 201910707951.5,授权公告日:2022.3.25.



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