张兴杰

张兴杰


  张兴杰


  博士,副教授,河南省优青,硕士生导师

  E-mail: zhangxingjie@htu.edu.cn


教育及工作经历:

2023.04 - 至今,河南师范大学,化学化工学院,副教授

2018.07 - 2023.04,河南师范大学,化学化工学院,讲师

2013.09 - 2018.06,中国科学院大学,上海有机化学研究所,有机化学专业,理学博士(硕博连读),导师:刘元红 研究员

2009.09 - 2013.06,洛阳师范学院,化学化工学院,应用化学专业,理学学士

研究兴趣和领域:

利用过渡金属催化的策略,通过巧妙地设计和开发新型配体,发展新颖、高效的催化体系,解决有机合成中长期存在的难点和挑战性问题,主要集中于:

1) 基于发展新试剂与新反应的合成方法学研究

2) 基于廉价过渡金属如镍、铜等催化的新型、绿色交叉偶联反应研究

Publications:

(10) Zhang, X.;* Cui, S.; Wei, S.; Zhao, M.; Liu, X.;* Zhang, G.* Nickel-Catalyzed Deaminative Alkyl-Alkyl Cross-Coupling of Katritzky Salts with Cyclopropanols: Merging C-N and C-C Bond Activation. Org. Lett. 2024, doi:10.1021/acs.orglett.4c00424.


(9) Liu, X.; Jiao, C.; Cui, S.; Liu, Q.; Zhang, X.;* Zhang, G.* Recent Advances in Nickel-Catalyzed Synthesis of Allenes: New Insights and Perspectives. ChemCatChem 2023, 15, e202300601. (Invited Review)



(8) Qi, D.; Zhang, X.;* Wang, X.; Liu, X.; Zhang, Z.; Shi, L.; Zhang, G.* Nickel-Catalyzed Reductive Iminoarylation of Oxime Ester-Tethered Alkenes: Rapid Entrance to Diverse Functionalized Pyrrolines. Org. Lett. 2023, 25, 1126-1130. (Highlighted by Synfacts)

(7) Zhang, X.;* Wang, X.; Jiao, C.; Zhao, J.; Liu, X.; Zhang, Z.; Zhang, G.* Transition-metal-free, Mild and Efficient Ring Expansion of Amino Acid Derivatives: Facile Access to Densely Functionalized Azepines. Org. Chem. Front. 2022, 9, 5516-5522.

(6) Zhang, X.;* Jiao, C.; Qi, D.; Liu, X.; Zhang, Z.; Zhang, G.Nickel-Catalyzed Deaminative Allenylation of Amino Acid Derivatives: Catalytic Activity Enhanced by an Amide-Type NN2 Pincer Ligand. Org. Lett. 2022, 24, 5361-5365. (Highlighted by CBG news and Organic Chemistry Portal)

(5) Zhang, X.;Qi, D.; Jiao, C.; Zhang, Z.; Liu, X.; Zhang, G.* Ni-Catalyzed Direct Iminoalkynylation of Unactivated Olefins with Terminal Alkynes: Facile Access to Alkyne-Labelled Pyrrolines. Org. Chem. Front. 2021, 8, 6522-6529.

(4) Zhang, X.;Qi, D.; Jiao, C.; Liu, X.; Zhang, G.* Nickel-Catalyzed Deaminative Sonogashira Coupling of Alkylpyridinium Salts Enabled by NN2 Pincer Ligand. Nat. Commun. 202112, 4904. (Featured in Org. Chem. Highlights)

Prior to HNU (Henan Normal University)

(3) Zhang, X.; Xie, X.; Liu, Y.* Nickel-Catalyzed Highly Regioselective Hydrocyanation of Terminal Alkynes with Zn(CN)2 Using Water as the Hydrogen Source. J. Am. Chem. Soc. 2018, 140, 7385-7389.

(2) Zhang, X.; Xia, A.; Chen, H.; Liu, Y.* General and Mild Nickel-Catalyzed Cyanation of Aryl/Heteroaryl Chlorides with Zn(CN)2: Key Roles of DMAP. Org. Lett. 2017, 19, 2118-2121.

(1) Zhang, X.; Xie, X.; Liu, Y.* Nickel-Catalyzed Cyclization of Alkyne-Nitriles with Organoboronic Acids Involving anti-Carbometalation of Alkynes. Chem. Sci. 2016, 7, 5815-5820.


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