刘统信

刘统信

                                  刘统信

                              博士,副教授,硕士生导师

                              河南省教育厅学术技术带头人

                              河南省高校科技创新人才 

                              河南师范大学青年骨干教师

                              Email: liutongxin@htu.edu.cn and liutongxin_0912@126.com


                            

教育与研究经历

2017年1月—至今              河南师范大学            化学化工学院  副教授

2012年8月—2016年12月  河南师范大学            化学化工学院  讲师

2007年9月—2012年6月    中国科学技术大学    化学与材料科学学院             理学博士

2005年9月—2007年6月    山东师范大学           化学化工与材料科学学院     理学学士

研究领域与兴趣富勒烯化学,绿色有机合成化学,金属有机化学

近年来主持的主要科研项目:

1. 国家自然科学基金 (U1904181): 新型开孔富勒烯的设计、合成与光伏性能研究

2. 河南省高校科技创新人才支持计划 (18HASTIT006)

3. 中国博士后科学基金特别资助 (2015T80769): 富勒烯氮杂衍生物合成

4. 国家自然科学基金 (21302044): 新型富勒烯含氮杂环化合物的合成及其衍生化研究

5. 国家自然科学基金 (U1304524): 新型富勒烯碳杂稠环衍生物材料的合成与性能研究

6. 中国博士后科学基金面上一等资助 (2013M530339): 利用串联反应构建新型杂环富勒烯衍生物研究

7. 河南师范大学优秀青年科学基金 (14YQ004): 芳基酰胺化合物在构建结构多样性富勒烯衍生物中的应用

代表性论文

29.Tong-Xin Liu,* Yifei Ru, Wenyue Guo, Nana Ma,* Panting Yang, Xiaojun Li, Pengling Zhang, Jingjing Bi, Guisheng Zhang*

Catalytic System-Controlled Regioselective 1,2- and 1,4-Carboannulations of [60]Fullerene

Org. Lett., 2024262552−2557.

         

28. Di Chao, Tong-Xin Liu,* Pengling Zhang, Shilu Xia, Panting Yang, Mengjiao Huang, Qingfeng Liu, Guisheng Zhang*

Interrupted N‑Heterocyclic Carbene-Catalyzed Radical Coupling Strategy: A Versatile Platform for Alkylation and 

Arylation of [60]Fullerene

Org. Lett., 2024261432−1436.

• Highlighted by CBG News

     

27. Tong-Xin Liu,* Xin Wang, Shilu Xia, Muqing Chen,* Mingjie Li, Panting Yang, Nana Ma, Ziqi Hu, Shangfeng Yang,*

Guisheng Zhang,* Guan-Wu Wang*

Dearomative Ring-Fused Azafulleroids and Carbazole -Derived Metallofullerenes: Reactivity Dictated by Encapsulation 

in a Fullerene Cage

Angew. Chem. Int. Ed., 2023, 62, e202313074.

• Highlighted by X-MOL

• Highlighted by CBG News

      

26. Di Chao, Tong-Xin Liu,* Pengling Zhang, Shilu Xia, Guisheng Zhang*

Copper-Mediated Radical-Induced Ring-Opening Relay Cascade Carboannulation Reaction of [60]Fullerene with 

Cyclobutanone Oxime Esters: Access to [60]Fullerene-Fused Cyclopentanes

J. Org. Chem., 2023, 88, 13076−13088.

 

25. Tong-Xin Liu,* Pangting Yang, Nana Ma, Xiaojun Li, Xin Wang, Jinliang Ma, Guisheng Zhang*

Synthesis of [60]Fullerene-Fused Allylbenzofurans via Palladium-Catalyzed Migration Reaction

Chin. J. Chem., 202341, 1733−1739.

• Invitation for a Special Issue on Recent Advances in Fullerene Chemistry

• Selected as the Inside Back Cover 

     

24. Tong-Xin Liu,* Xin Wang, Pengling Zhang, Panting Yang, Xiaojun Li, Guisheng Zhang*

Assembly of Diverse [60]Fullerene-Fused Tricyclic Scaffolds via a Palladium-Catalyzed Cascade [2 + 2 + 2] Annulation 

Reaction

Org. Lett., 202224, 9102−9106. 

• Highlighted by 化学深耕堂

     

23. Tong-Xin Liu,* Chuanjie Zhang, Pengling Zhang, Xin Wang, Jinliang Ma, Guisheng Zhang*

Palladium-catalyzed decarboxylative [2 + 3] cyclocarbonylation reactions of [60]fullerene: selective synthesis of 

[60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes  

Org. Chem. Front., 20229, 5564−5570. 

      


22. Tong-Xin Liu,* Xue Zhu, Shilu Xia, Xin Wang, Pengling Zhang, Guisheng Zhang* 

NHC-Catalyzed Three-Component Hydroalkylation Reactions of [60]Fullerene: An Umpolung Approach to Diverse 

Monoalkylated Hydrofullerenes

Org. Lett., 202224, 3691−3695. 

• Highlighted by Synfacts, 202218, 0857. 

• Highlighted by CBG News

      

21. Tong-Xin Liu,* Han Wu, Nana Ma, Chuanjie Zhang, Pengling Zhang, Jinliang Ma, Guisheng Zhang* 

Acid-Responsive Dissociation of Ferrocene Compounds: Diels−Alder Diene Equivalents for Selective Preparation of 

[60]Fullerene-Fused Bicyclo[2.2.1]hept-5-enes

J. Org. Chem.2022, 87, 3104−3113. 

   

20. Jinliang Ma, Tong-Xin Liu,* Pengling Zhang, Xuna Zhao, Guisheng Zhang* 

Metal-Free-Catalyzed Three-Component [2+2+2] Annulation Reaction of [60]Fullerene, Ketones, and Indoles: Access 

to Diverse [60]Fullerene-Fused 1,2-Tetrahydrocarbazoles

Org. Lett., 2021, 23, 1775−1781.

  

19. Jinliang Ma, Tong-Xin Liu,* Pengling Zhang, Chuanjie Zhang, Guisheng Zhang* 

Palladium-catalyzed domino spirocyclization of [60]fullerene: synthesis of diverse [60]fullerene-fused spiro[4,5]

/[5,5] derivatives 

Chem. Commun., 202157, 49−52.

• Selected as the Inside Front Cover 

• Highlighted by X-MOL

• Highlighted by RSC China

     

18. Conghui WuTong-Xin Liu,* Pengling Zhang, Xue Zhu, Guisheng Zhang*

Iron-Catalyzed Redox-Neutral Radical Cascade Reaction of [60]Fullerene with γ,δ-Unsaturated Oxime Esters: 

Preparation of Free (N–H) Pyrrolidino[2¢,3¢:1,2]fullerenes 

Org. Lett., 2020, 227327−7332. 

• Highlighted by CBG News

     

17. Qingfeng Liu, Tong-Xin Liu,* Jinliang Ma, Guisheng Zhang*

Palladium-Catalyzed Three-Component Tandem Coupling−Carboannulation Reaction Leading to Polysubstituted 

[60]Fullerene-Fused Cyclopentanes 

Org. Lett., 202022, 284−289. 

• Highlighted by CBG News  

   

16. Qingfeng Liu, Tong-Xin Liu,* Yifei Ru, Xue Zhu, Guisheng Zhang*

Palladium-catalyzed decarboxylative heterocyclizations of [60]fullerene: preparation of novel vinyl-substituted 

[60]fullerene-fused tetrahydrofurans/pyrans/quinolones

Chem. Commun., 201955, 14498−14501.

     

15. Tong-Xin Liu,* Juan Wei, Pengling Zhang,* Yifei Ru, Jinliang Ma, Xingjie Zhang, Nana Ma, Guisheng Zhang* 

Copper-Catalyzed N−H/C−H Sequential Relay Oxidative Radical Carboannulation: Construction of Diversely 

Substituted [60]Fullerene-Fused Tetrahydrocyclopenta[b]indoles

Org. Lett., 201921, 6461−6465.        

• Highlighted by CBG News

       

14. Qingfeng Liu, Tong-Xin Liu,* Nana Ma, Chenhao Tu, Ruoya Wang, Guisheng Zhang*  

Cu(II)/Mn(III)-Promoted Synergistic Radical N‑Heteroannulation Reaction: Synthesis of [60]Fullerene-Fused Tetrahydroquinoline Derivatives    

J. Org. Chem.2019, 84, 7255−7264.

    

13. Tong-Xin Liu,* Shuaishuai Yue, Changgeng Wei, Nana Ma,*Pengling Zhang, Qingfeng Liu, Guisheng Zhang*

Solvent-promoted catalyst-free regioselective N-incorporation multicomponent domino reaction: rapid assembly of 

π-functionalized [60]fullerene-fused dihydrocarbolines 

Chem. Commun.201854, 13331−13334.

• Selected as the Outside Front Cover   

   

12Beibei Hu, Tong-Xin Liu,* Pengling Zhang, Qingfeng Liu, Jingjing Bi, Lei Shi, Zhiguo Zhang, Guisheng Zhang*

NHeterocyclic Carbene-Catalyzed α,β-Unsaturated Aldehyde Umpolung in Fullerene Chemistry: Construction of 

[60]Fullerene-Fused Cyclopentan-1-ones and Cyclohex-2-en-1-ones

Org. Lett., 2018204801−4805.

• Highlighted by Synfacts, 2018, 14, 1303. 

• Highlighted by CBG News

     

11. Tong-Xin Liu,Shaoshuai Hua, Nana Ma, Pengling Zhang, Jingjing Bi, Zhiguo Zhang, Guisheng Zhang*

Reactivity and Synthetic Applications of a-Functionalized Oxime Acetates: Divergent Access to Fulleropyrrolidines and 

Mono- and Disubstituted 1-Fulleropyrrolines via Copper-Catalyzed Redox-Neutral N-Heteroannulation with 

[60]Fullerene

Adv. Synth. Catal.2018360, 142−152.  

     

10. Shilu Xia, Tong-Xin Liu,Pengling Zhang, Jinliang Ma, Qingfeng Liu, Nana Ma, Zhiguo Zhang, Guisheng Zhang*

Broad Synthesis of Disubstituted Dihydrofuran-Fused [60]Fullerene Derivatives via Cu(I)/Ag(I)-Mediated Synergistic 

Annulation Reaction

J. Org. Chem., 201883, 862−870. 

• Highlighted by Synfacts, 201814, 0369.

 

9. Di Chao, Tong-Xin Liu,* Nana Ma, Pengling Zhang, Zheng Fu, Jinliang Ma, Qingfeng Liu, Fengjin Zhang, Zhiguo Zhang,

Guisheng Zhang*

Silver(I)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to 

diverse disubstituted [60]fullerene-fused dihydropyrroles

Chem. Commun.201652, 982−985.

   

8Tong-Xin Liu,* Jinliang Ma, Di Chao, Pengling Zhang, Nana Ma, Qingfeng Liu, Lei Shi, Zhiguo Zhang, Guisheng Zhang*

Synthesis of C60-Fused Tetrahydrocarbazole/Dibenzothiophene/Benzothiophene and Dibenzofuran Derivatives via Metal-

Free Oxidative Dehydrogenative Carboannulation

Org. Lett., 2016, 184044−4047.

     

7Tong-Xin Liu,* Jinliang Ma, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang, Guisheng Zhang*

AgNO2-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via 

radical cyclization with [60]fullerene

Chem. Commun.201551, 12775−12778.

     

6. Tong-Xin Liu,* Zhenbei Zhang, Qingfeng Liu, Pengling Zhang, Penghao Jia, Zhiguo Zhang, Guisheng Zhang*

Synthesis of [60]Fullerene-Fused Tetrahydroazepinones and Azepinonimines via Cu(OAc)2-Promoted N-Heteroannulation Reaction

Org. Lett., 2014161020−1023.

    

5. Tong-Xin Liu,* Yuquan Liu, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang, Guisheng Zhang*

Iron-Mediated Internal-Oxidant Relay Cascade Reaction: Strategy to Synthesize Fullerenooxazoles and Hydroxyfullerenyl Amides

J. Org. Chem., 2014, 79, 11084−11090. 

 

4. Tong-Xin Liu, Fa-Bao Li, Dian-Bing Zhou, Guan-Wu Wang*

Ferric Perchlorate Promoted Reaction of [60]Fullerene with N−Sulfonyl Aldimines: Synthesis and Functionalization of 

Fulleroxazolidines

J. Org. Chem., 201580, 11986−11992. 

 

3Tong-Xin Liu, Tao Wei, San-E Zhu, Guan-Wu Wang*, Mingzhi Jiao, Shangfeng Yang*, Faye L. Bowles, Marilyn M. Olmstead*, Alan L. Balch*

Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids of Sc3N@Ih-C80

J. Am. Chem. Soc.2012134, 11956−11959.

 

2Tong-Xin Liu, Fa-Bao Li, Guan-Wu Wang*

Synthesis of [60]Fullerene-Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum 

Chloride

Org. Lett., 2011136130−6133.

     

1. Guan-Wu Wang,Tong-Xin Liu, Mingzhi Jiao, Nan Wang, San-E Zhu, Chuanbao Chen, Shangfeng Yang*, Faye L. Bowles, 

Christine M. Beavers, Marilyn M. Olmstead *, Brandon Q. Mercado, Alan L. Balch*

The Cycloaddition Reaction ofIh-Sc3N@C80with 2-Amino-4,5- diisopropoxybenzoic Acid and Isoamyl Nitrite to 

Produce an Open-Cage Metallofullerene

Angew. Chem., Int. Ed.2011, 50, 4658−4662.

   

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