曹厚继
博士,副教授(校聘),硕士生导师
E-mail: caohouji@htu.edu.cn
Office: N-417
ORCID: https://orcid.org/0000-0002-0539-9124
课题组主页:http://www.boronchemistry.net
教育经历
2016.08-2021.09 南京大学 化学化工学院 化学 理学博士
2013.09-2016.07 河南师范大学 化学化工学院 无机化学 理学硕士
2009.09-2013.07 河南师范大学 化学与环境科学学院 化学 理学学士
工作经历
2022.02-至今 河南师范大学 化学化工学院 副教授(校聘)
研究领域与兴趣
硼化学,金属有机化学,功能导向的精准有机合成方法学,配位化学
科研项目
1. 国家自然科学基金青年项目:α-羰基亚砜叶立德参与的碳硼烷并硼杂环化合物的精准合成(22201067,2023.01-2025.12),主持
2. 河南师范大学博士启动课题,校20230206,2023.01-2025.12,主持
3. 国家自然科学基金重大研究计划:硼簇衍生物在硼中子捕获疗法抗癌中的应用(91961104,2020.01-2022.12),参与
4. 国家自然科学基金国际(地区)合作与交流项目:硼簇功能化新方法及潜在应用(21820102004,2019.01-2023.12),参与
论文
11. Fangxiang Sun, Shuaimin Tan, Hou-Ji Cao, Chang-ShengLu, Deshuang Tu*, Jordi Poater, Miquel Solà* and Hong Yan*, Facile Construction of New Hybrid Conjugation via Boron Cage Extension, J. Am. Chem. Soc., 2023, 145, 3577-3587. (SCI一区Top, IF = 16.383)
10. Yingying Wang, Hui Han, Jia-Xin Kang, Jiamin Peng, Xiongxiong Lu, Hou-Ji Cao, Zhenxing Liu* and Xuenian Chen*, Silylium Ion-Mediated Cage-Opening Functionalization of Closo-B10H102− Salts, Chem. Commun., 2022, 58, 11933-11936. (SCI二区Top, IF = 6.065)
9. Bin Wang, Hongyuan Ren, Hou-Ji Cao*, Chang-ShengLu* and Hong Yan*, A Switchable Redox Annulation of 2-Nitroarylethanols Affording N-heterocycles: Photoexcited Nitro as a Multifunctional Handle. Chem. Sci., 2022, 13, 11074-11082. (SCI一区Top, IF = 9.969)
8. Fangxiang Sun, Shuaimin Tan, Hou-Ji Cao, Jingkai Xu, Vladimir I. Bregadze, Deshuang Tu*, Chang-ShengLu* and Hong Yan*, Palladium-Catalyzed Hydroboration of Alkynes with Carboranes: Facile Construction of a Library of Boron Cluster-Based AIE-Active Luminogens, Angew. Chem. Int. Ed., 2022, 61, e202207125. (SCI一区Top, IF = 16.823)
7. Hou-Ji Cao, Xing Wei, Fangxiang Sun, Xiaolei Zhang*, Chang-ShengLu* and Hong Yan*, Metal-Catalyzed B–H Acylmethylation of Pyridylcarboranes: Access to Carborane-Fused Indoliziniums and Quinoliziniums, Chem. Sci., 2021, 12, 15563-15571. (SCI一区Top, IF = 9.825)
6. Hou-Ji Cao, Meng Chen, Fangxiang Sun, Yue Zhao, Chang-Sheng Lu, Xiaolei Zhang*, Zhuangzhi Shi* and Hong Yan*, Variable Metal Chelation Modes and Activation Sequence in Pd-Catalyzed B−H Poly-Arylation of Carborane, ACS Catal., 2021, 11, 14047-14057. (SCI一区Top, IF = 13.084)
5. Chun-Xiao. Li, Qian Ning, Wenxuan Zhao, Hou-Ji. Cao, Yi-Ping. Wang, Chang-ShengLu*, Yong Liang* and Hong Yan*, Rh‐Catalyzed Decarbonylative Cross‐Coupling Between o‐Carboranes and Twisted Amides: A Regioselective, Additive‐Free and Concise Late‐stage Carboranylation, Chem–Eur. J., 2021, 27, 2699-2706. (SCI二区Top, IF = 5.236)
4. Hou-Ji Cao, Huimin Dai, Xiaolei Zhang, Hong Yan* and Chang-Sheng Lu*, Synthesis and Characterization of Cp*Ir-Dithiolene-o-Carborane Phosphine Complexes: A Continuous Investigation of B−H⋯π Interaction, Mol. Phys., 2019, 117, 1287-1297. (SCI三区, IF = 1.962)
3. Qianyi Zhao, Xin-Ting. Guan, Ting Dou, Hou-Ji. Cao, Na-Na Ma, Ting Xu, Peng-Hui. Gao, Xiao-Hua Kong, Jie Zhang, Xuenian Chen, Synthesis and Characterization of Bis(Pyrazolyl)Borate Ni(II) Complexes: Ligand Rearrangement and Transformation, Dalton Trans., 2019, 48, 13242-13247. (SCI二区, IF = 4.174)
2. Chun-Xiao Li, Hao-Yun. Zhang, Tsz-Yung Wong, Hou-Ji Cao, Hong Yan* and Chang-Sheng. Lu*, Pyridyl-Directed Cp*Rh(III) Catalyzed B(3)−H Acyloxylation of o-Carborane, Org. Lett., 2017, 19, 5178-5181. (SCI一区Top, IF = 6.492)
1. Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang*, Lai-Sheng Wang*, Xuenian Chen*, Catalyst Design Based on Agostic Interactions: Synthesis, Characterization, and Catalytic Activity of Bis(Pyrazolyl)Borate Copper Complexes, Dalton Trans., 2016, 45, 10194-10199. (SCI二区, IF = 4.029)
学术会议
♦ 第2届国际硼化学学术会议(ICBC-II);太原;2019. 07.
♦ 第28届国际金属有机化学会议;佛罗伦萨;2018. 07.
♦ 第二十届全国金属有机化学学术讨论会;南京;2018. 11.
♦ 中国化学会第十届全国有机化学学术会议;深圳;2017. 12.
♦ 第16届国际硼化学会议;香港;2017. 07.