赵玉灵

赵玉灵

 


姓名:赵玉灵

博士,教授,博士生导师。2008年起一直从事离子液体领域的研究,在研究离子液体及混合物体系的微观结构、相互作用等基础性研究,以及CO2转化、生物质溶解等应用领域取得了一系列成果,已在Angew. Chem. In. Ed., ACS Catal. Green Chem., ChemSusChem, ACS Sustain. Chem. & Eng.等国内外重要期刊发表学术论文50余篇,被国内外同行引用1200多次。获得河南省优秀博士学位论文奖,河南省自然科学论文一等奖1 项,二等奖2 项,获得授权国家发明专利5项。主持国家自然科学基金2项,省优秀青年基金1项,省高校科技创新人才1项等

联系方式:

E-mail: ylzhao@htu.edu.cn 


 

 

教育与研究经历

2008.09-2013.06  河南师范大学  物理化学  理学博士

2023.07-2023.11  日本大阪大学  计算化学  访问学者

2013.07-2017.12  河南师范大学化学化工学院 讲师

2017.12-2024.02  河南师范大学化学化工学院 副教授

2024.02-至今     河南师范大学化学化工学院 教授

 

主讲课程:

模拟化学方法,物理化学,物理化学实验


研究领域与兴趣

1. 离子液体的构效关系及相互作用研究

2. 多孔材料的分子设计及性能调控


近年来主持的主要科研项目:

1国家自然科学基金面上项目2018.1-2021.12主持

2国家自然科学基金青年科学基金项目2015.1-2017.12主持

(3) 河南省优秀青年基金,2024.01-2026.12,主持

(4) 河南省高校科技创新人才,2020.01-2021.12,主持 

(5) 中国博士后科学基金第11批特别资助2018.6-2021.06主持

(6中国博士后科学基金第62批面上资助2017.11-2021.06主持

(7河南省高等学校重点科研项目,2014.1-2015.12,主持

(8河南师范大学优秀青年科学基金,2017.6-2020.6主持


代表性论文: 

(24) Y. Zhao, X. Xu, K. Zhang, Z.. Li, H.. Wang, Y. Zhao, J. Qiu*, J.. Wang*, Designing Local Electron-delocalization in 2D Covalent Organic Frameworks for Enhanced Sunlight-Driven Photocatalytic Activity. ACS Catal., 2024, 14, 3556-3664.

(23) Y. Zhao *, K. Zhang, K. Zhu, Y. Zhao, H.. Zhai, J. Qiu *, Missing-linker Defects in Covalent Organic Framework Photocatalyst for highly efficient Synthesis of Tetrahydroquinoline. Green Chem., 2024, 26(5), 2645-2652.

(22) Y. Zhao *, X. Wang, Z. Li, H. Wang, Y. Zhao, J. Qiu*, Understanding the Positive Role of Ionic Liquids in CO2 Capture by Poly(ethylenimine), J. Phys. Chem. B, 2024, 128(4): 1079-1090.

(21) J. Qiu,C. Xu, X. Xu,Z. Li, H. Wang, Y. ;Zhao, Y. Zhao,* An ultrastable cationic covalent organic framework for selective capture of silver from aqueous solution. J. Mol. Struct., 2023, 1292, 136173.

(20) J. Qiu*, C. Xu, X. Xu, Y. Zhao, Y. Zhao, Y. Zhao *; J. Wang *, Porous Covalent Organic Framework Based Hydrogen-Bond Nanotrap for the Precise Recognition and Separation of Gold, Angew. Chem. Int. Ed., 2023, 62, e202300459

(19) Y. Zhao, C. Xu, J. Qiu*, Z. Li, H.. Wang, J. Wang *, Tailoring Delicate Pore Environment of 2D Covalent Organic Frameworks for Selective Palladium Recovery, Chem. Eng. J., 2022, 446,136823

(18) Y. Zhao, Y. Zhao, C. Wu, J. Qiu, H. Wang, Z. Li, Y. Yang, J. Wang*, An Ultrastable Crystalline Acylhydrazone-Linked Covalent Organic Framework for Efficient Removal of Organic Micropollutants from Water. Chem. Eur. J., 2021, 27(36): 9391-9397.

(17) Y. Zhao, L. Shi, J. Qiu, H. Wang, Z. Li, X. Liu, J. Fan*, J. Wang*, Impact of alkyl chain length of temperature-responsive ionic liquids on the aggregation behavior in ionic liquid microemulsions. J. Mol. Liq., 2021, 326: 115282 .

(16)Y. Zhao, Y. Zhao, J. Qiu, Z. Li, H. Wang, J. Wang*, Facile Grafting of Imidazolium Salt in Covalent Organic Frameworks with Enhanced Catalytic Activity for CO2 Fixation and the Knoevenagel ReactionACS Sustain. Chem. Eng., 2020, 8(50):18413-18419.

(15) J. Qiu, H. Wang , Y. Zhao*, P. Guan, Z. Li, H. Zhang, H. Gao, S. Zhang, J. Wang*, Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C-C coupling reactions, Green Chem., 2020, 22(8):2605-2612.

(14) Y. Zhao, L. Shi, J. Qiu, Y. Pei, H. Wang, Z. Li, Jing Fan*, J. Wang*, Mechanism of emulsification and demulsification for temperature-sensitive ionic liquid microemulsion. J. Mol. Liq., 2020, 319:114352.

(13) J. Qiu, Y. Zhao, Y. Zhao,*, H. Wang, Z. Li, J. Wang,* T. Jiao, Cu(I)/Ionic Liquids Promote the Conversion of Carbon Dioxide into Oxazolidinones at Room Temperature, Molecules, 2019, 24: 1241.

(12) J. Qiuƚ, Y. Zhaoƚ, Z. Li, H. Wang*, Y. Shi, J. Wang*, Imidazolium-Salt-Functionalized Covalent Organic Frameworks for Highly Efficient Catalysis of CO2 Conversion, Chemsuschem, 2019, 12(11): 2421-2427

(11) Y. Zhao*, L. Tian, Y. Pei, H. Wang, J. Wang*, Effect of Anionic Structure on the LCST Phase Behavior of Phosphonium Ionic Liquids in WaterInd. Eng. Chem. Res., 2018, 38(57): 12935-12941

(10) Y. Zhao, Qiu J., Z. Li, H. Wang, M. Fan, J. Wang*, An experimental and theoretical study on the unexpected catalytic activity of triethanolamine for the carboxylative cyclization of propargylic amines with CO2, ChemSusChem, 2017,10(9):2001-2007

(9) Y. Zhao, L. Tian, J. Qiu, Z. Li, H. Wang, G. Cui, S. Zhang, J. Wang*, Remarkable synergistic effect between copper(I) and ionic liquids for promoting chemical fixation of CO2, J. CO Util., 2017, 22:374-381

(8) Y. Zhao, J. Qiu, L. Tian, Z. Li, M. Fan, J. Wang*, New copper(I)/DBU catalyst system for the carboxylative cyclization of propargylic amines with atmospheric CO2: an experimental and theoretical study, ACS Sustain. Chem. Eng.,2016, 4(10):5553-5560

(7) Y. Zhao, H. Wang, Y. Pei, Z. Liu, J. Wang*, Understanding the mechanism of LCST phase separation of mixed ionic liquids in water by MD simulations, Phys. Chem. Chem. Phys., 2016, 18(33):23238-23245

(6) Y. Zhao, J. Wang*, H. Wang, Z. Li, X. Liu, S. Zhang, Is there any preferential interaction of ions of ionic liquids with DMSO and H2O? A comparative study from MD simulation, J. Phys. Chem. B, 2015, 119(22):6686-6695

(5) Y. Zhao, X. Liu, J. Wang*, S. Zhang*, Insight into co-solvent effect on cellulose dissolution in imidazolium-based ionic liquid solvent systems. J. Phys. Chem. B., 2013,117(30): 9042-9049,

(4) Y. Zhao, X. Liu, J. Wang*, S. Zhang*, Effects of anionic structure on cellulose dissolution in ionic liquids: A molecular dynamics simulation. Carbohyd. Polym., 2013, 94(2): 723-730

(3) Y. Zhao, X. Liu, X. Lu*, J. Wang*, S. Zhang, H. Wang, G. Gurau, R. Rogers*, L. Su, H. Li, The Behavior of Ionic Liquids under High Pressure: A Molecular Dynamics Simulation, J. Phys. Chem. B., 2012, 116(35): 10876-10884

(2) Y. Zhao, X. Liu, J. Wang*, S. Zhang*, Effects of cationic structure on cellulose dissolution in ionic liquids: A molecular dynamics study,ChemPhysChem, 2012, 13(13), 3126-3133

(1) Y. Zhao, K. Dong, X. Liu, S. Zhang*, J. Zhu, J. Wang*, Structure of ionic liquids under external electric field: a molecular dynamics simulation. Mol. Sim., 2012, 38(3), 172-178


成果奖励:

1赵玉灵,离子液体及其混合物的分子动力学模拟,河南省优秀博士学位论文,河南省教育厅,2015

(2赵玉灵Insight into co-solvent effect on cellulose dissolution in imidazolium-based ionic liquid solvent systems河南省优秀科技论文一等奖2017

(3赵玉灵,刘晓敏,吕兴梅,张锁江,王键吉,The behavior of ionic liquids under high pressure: a molecular dynamics simulation河南省自然科学优秀学术论文一等奖2013

4赵玉灵,刘晓敏,王键吉,张锁江,Effects of cationic structure on cellulose dissolution in ionic liquids: a molecular dynamics study河南省自然科学优秀学术论文二等奖2013

  

授权发明专利:

(1)赵玉灵;刘丽;仇记宽;王键吉;一种在室温常压下催化CO2合成2-恶唑烷酮类化合物的方法,2019-4-23,中国,ZL 201710307639.8. 

(2)赵玉灵;田利;王键吉;姚美焕;仇记宽;一种利用醇胺催化CO2合成2-恶唑烷酮类化合物的方法,2018-8-21,中国,ZL 201610884188.X. 

(3)赵玉灵;仇记宽;一种羧甲基胍胶交联剂及其制备方法和应用,2019-8-1, 中国,ZL201410590856.9.

(4)赵玉灵;仇记宽;一种简便合成3,3-二氟环己基甲胺的方法,2016-4-6,中国,CN201410590569.8. 



 
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