个人简介:柴国利,女,博士,硕士生导师,E-mail: guolichai@126.com
教育经历:
2007.09-2011.06 信阳师范学院 化学化工学院,化学教育专业,理学学士;
2011.09-2014.06 大连理工大学 化学化工学院,应用化学专业,工学硕士;
2014.09-2017.12 中国科学院上海有机化学研究所,有机化学专业,理学博士。
工作经历:
2018.01-现在 河南师范大学化学化工学院 有机化学研究所 讲师。
研究领域与兴趣:
1、功能有机分子的设计与合成;
2、不对称催化;
近年来主持的主要科研项目:
1、河南省自然科学基金-青年科学基金项目(232300421371, 2023.01-2024.12)
2、河南省高等学校重点科研项目(21A150028, 2021.01-2022.12)
3、河南师范大学国家级科研项目培育基金-青年培育(2020PL20, 2020.01-2022.12)
4、河南师范大学博士科研启动课题(qd18005, 2019.01-2021.09)
代表性论文:
1、Xiao Wang, Guo-Li Chai,* Ya-Jing Hou, Ming-Qian Zhou, Junbiao Chang.* Enantioselective Synthesis of Chiral Organosilicon Compounds by Organocatalytic Asymmetric Conjugate Addition of Boronic Acids to β‑Silyl-α,β-Unsaturated Ketones. J. Org. Chem. 2023, 88(5), 3254–3265.
2、Guo-Li Chai,*# En-Ze Yao,# Rui-Hao Liu, Junbiao Chang.* Chiral-Boron-Complex-Catalyzed Asymmetric [3 + 2] Cycloaddition of 2′-Hydroxychalcones with N,N′‑Cyclic Azomethine Imines. Org. Lett. 2022, 24(35), 6449–6454.
3、Guo-Li Chai,* Ping Zhang, En-Ze Yao, Junbiao Chang.* Enantioselective Conjugate Addition of Boronic Acids to α,β-Unsaturated 2-Acyl Imidazoles Catalyzed by Chiral Diols. J. Org. Chem. 2022, 87(14), 9197–9209.
4、En-Ze Yao, Guo-Li Chai,* Ping Zhang, Bo Zhu, Junbiao Chang.* Chiral dihydroxytetraphenylene-catalyzed enantioselective conjugate addition of boronic acids to β-enaminones. Org. Chem. Front. 2022, 9(9), 2375–2381.
5、Lu Zhao,# En-Ze Yao,# Guo-Li Chai,* Shi-Yu Ma, Junbiao Chang.* Organocatalyzed Enantioselective Conjugate Addition of Boronic Acids to β,γ-Unsaturated α-Ketoesters. J. Org. Chem. 2021, 86(24), 18211–18223.
6、Ping Zhang, Guo-Li Chai,* En-Ze Yao, Li-Xiao Guo, Xue-Yu Liu, Junbiao Chang.* Asymmetric Double-Conjugate Addition of Alkenylboronic Acids to Dienones Catalyzed by Chiral Diols. Org. Chem. Front. 2021, 8(7), 1575–1580.
7、Guo-Li Chai,* Yan Qiao, Ping Zhang, Rong Guo, Juan Wang, Junbiao Chang.* Chiral Hydroxytetraphenylene-Boron Complex-Catalyzed Asymmetric Diels-Alder Cycloaddition of 2'-Hydroxychalcones. Org. Lett. 2020, 22(20), 8023–8027.
8、Guo-Li Chai,* A-Qiang Sun, Dong Zhai, Juan Wang, Wei-Qiao Deng, Henry N. C. Wong, Junbiao Chang. Chiral Hydroxytetraphenylene-Catalyzed Asymmetric Conjugate Addition of Boronic Acids to Enones. Org. Lett. 2019, 21(13), 5040–5045.
9、Guo-Li Chai, Bo Zhu, Junbiao Chang.* Synthesis and Application of Substituted 1,16-Dihydroxytetraphenylenes in Catalytic Asymmetric Allylboration of Ketones. J. Org. Chem. 2019, 84(1), 120–127.
10、Guo-Li Chai, Jian-Wei Han, Henry N. C. Wong.* Asymmetric Darzens Reaction of Isatins with Diazoacetamides Catalyzed by Chiral BINOL-Titanium Complex. J. Org. Chem. 2017, 82(23), 12647–12654.
11、Guo-Li Chai, Jian-Wei Han, Henry N. C. Wong.* Hydroxytetraphenylenes as Chiral Ligands: Application to Asymmetric Darzens Reaction of Diazoacetamide with Aldehydes. Synthesis 2017, 49(1), 181–187.